The 39-year-old was joined by husband Pitt as she attended the world premiere of her latest filmMonday, reports dailymail.co.uk.
The two walked down the aisle in August this year after two years of engagement.
Looking radiant in a strapless, fishtailed Gucci dress, Jolie greeted thousands of fans who lined the streets by the State Theatre here before walking on the red carpet.
“We just feel that much closer. It makes us happy to be married. I don’t think we needed it but it just feels like he’s my husband,” said Jolie.